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Colibactin

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Colibactin is a chemically unstable small molecule genotoxin produced by several bacteria (e.g., Colibactin-Producing Escherichia coli / E. coli pks +) in minute amounts, including members of the human gut microbiota
Nougayrède et al., 2006 Science 313: 848-851
Xue et al. 2019a Science 365: eaax2685
Auvray et al. 2021 Microbial Genomics 7: 000579

Natural colibactin remains non-isolatable
Xue et al. 2019a Science 365: eaax2685

Colibactin’s chemical structure and the molecular mechanism underlying its genotoxic effects have remained unknown for over a decade
Wilson et al. 2019a Science 363: eaar7785

Because the biosynthetic pathway of colibactin is only partially elucidated, t…