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cyclic GMP-AMP (cGAMP)

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Contents

This is a hybrid molecule that exists in different forms, such as 2'3'-cGAMP and 3'3'-cGAMP. In mammals, cGAMP is synthesized by the enzyme Cyclic GMP-AMP synthase (cGAS) in response to cytosolic DNA and plays a pivotal role in activating the cGAS-STING Pathway (Stimulator of Interferon Genes) pathway, leading to immune responses.

References:
Cai et al. 2023 bioRxiv [Preprint] 9: 2023.05.08.539652
Chen 2023 Org Chem 10(4): 1086-1098